气相色谱-质谱法测定鸡蛋中三聚氰胺

建立了气相色谱-质谱法测定鸡蛋中三聚氰胺的方法. 鸡蛋样品经三氯乙酸提取,乙酸铅沉淀蛋白后,过MCX阳离子交换固相萃取小柱除去样品基质干扰,用N,O-双三甲基硅基三氟乙酰胺(BSTFA)+三甲基氯硅烷(TMCS)(99+1)衍生,进行气相色谱-质谱分析. 在0.010~2.00 mg/L浓度范围内,线性关系良好(r=0.9996),检出限为0.01 mg/kg. 方法回收率为90.1%~94.7%,RSD为1.7%~5.3%. 方法准确、灵敏,适用于鸡蛋中三聚氰胺的检测.     

Synthesis and Biological Activities of Novel 1,2,4-Triazole Derivatives Containing 1,2,3-Thiadiazole Ring

A series of novel 1,2,4-triazole derivatives containing 1,2,3-thiadiazole ring was designed and synthesized. Their structures were confirmed by IR, 1^H NMR, high resolution mass spectrometer（HRMS） and electrospray ionization-mass spectromcter（ESI-MS） combined with melting points and elemental analysis. Preliminary bioassays indi- cate that these compounds exhibit good insecticidal activity against Aphis laburni at 100 μg/mL, especially compound 6b shows mortality of no less than 95%. Most of the compounds show good activities against tobacco mosaic virus（TMV） with different modes in vivo at 100 μg/mL. Compound 6d standed out, showing a good insecticidal activity and very high induction effects against TMV in vivo. Collectively, our data demonstrate a new strategy for insect and virus control.     

Vortex Street in Homogeneous Dense Dusty Magnetoplasma

For studying the vortex structure in uniform dense dusty astrophysical conditions, a two-dimensional nonlinear equation is derived employing the quantum magnetoplasma hydrodynamic model and considering the strong collisional effect. The coherent vortex solution is obtained by perturbation analysis method. It is shown that the distribution of the electrostatic potential forms spatially a periodic vortex street, and is controlled temporally by the arbitrary function of time that may lead to abundant spacial distributions. It is found that the dust charge number, collision frequency, electron Fermi wavelength and quantum correction all play significant roles to the spatial distribution of vortex street.     

枯水期鄱阳湖水体富营养化状态评价

通过对鄱阳湖水体氮、磷等营养盐的分析测定,采用综合营养状态指数水体富营养化评价法,对枯水期鄱阳湖水质进行了富营养化水平分析。研究结果显示,不论从单个指标,还是从综合营养状态指数进行评价,枯水期鄱阳湖的水质处于富营养化水平。与已有文献中的数据比较,近年鄱阳湖的水质没有明显恶化。根据不同采样地点的情况分析,判断其氮、磷等有机物主要来源于面源污染。     

半序概率度量空间中一类算子方程的可解性

半序方法是研究非线性算子方程问题的主要方法之一。利用概率度量空间中由泛函诱导的半序,在不同的压缩条件下,研究了非线性算子方程Lx=N(x,x)的可解性问题,所得结论推广和改进了有关文献中的一些结论。     

Anti-diabetic Effects of Polysaccharides from Ethanol-insoluble Residue of Schisandra chinensis(Turcz.) Baill on Alloxan-induced Diabetic Mice

The ethanol-insoluble residue of Schisandra generated during lignans industrial production is usually treated as solid waste. However, there is active polysaccharide which could be used in it. In this work, the water-soluble polysaccharides from the ethanol-insoluble residue of Schisandra(ESCP) were obtained and their anti-diabetic effect was evaluated. The results indicate that ESCP could significantly reduce the blood glucose level in alloxan-induced diabetic mice. Moreover, the ESCP could significantly improve the lipid metabolism and increase the content of liver glycogen in alloxan-induced diabetic mice. The results indicate that ESCP could be developed into a potential natural hypoglycemic agent.     

固相萃取-超高效液相色谱-串联质谱法检测婴幼儿奶粉中的7种链格孢霉毒素

婴幼儿奶粉配料中的植物油易受到链格孢霉菌污染,因而链格孢霉毒素(ATs)成为该类食品的重点检测对象.该研究建立了超高效液相色谱-串联质谱法快速检测婴幼儿奶粉中链格孢酚、链孢酚单甲醚、交链孢霉烯、细交链孢菌酮酸、腾毒素、交链孢毒素Ⅰ、细格菌素7种ATs的方法.通过参数优化确定最佳的质谱与色谱条件,选取BEH-C18色谱柱...     

LD侧面泵浦Nd∶GdVO4 532 nm绿光激光器

为了获得高功率窄脉宽532 nm绿光激光输出,通过高重复频率声光驱动调Q技术和LD侧面泵浦Nd∶GdVO4技术,获得高功率线偏振1 064 nm激光输出。采用内腔倍频方式,对非线性晶体KTP进行频率变换,实现高功率窄脉宽绿光激光输出。在电源输入电流30 A,调Q驱动频率10 kHz的条件下,获得最高功率30 W线偏振1 064 nm激光输出,脉宽30 ns,倍频KTP晶体获得23.4 W的532 nm绿光输出,1 064 nm到532 nm转化效率为78%。实验结果表明:通过声光调Q技术和LD侧面泵浦Nd∶GdVO4技术,可以实现高功率线偏振窄脉宽1 064 nm激光输出,倍频非线性晶体KTP可获得高功率窄脉宽532 nm激光。     

多光束泵浦中红外激光器

为了获得高功率高效率3 m～5 m中红外激光输出,利用双声光调Q晶体,通过高重复频率驱动调Q同步技术和LD侧面泵浦双棒串接技术,获得高功率高光束质量1.06 m激光双端输出,外置起偏器获得4束激光输出,利用波片偏振旋光原理,实现4束偏振态一致的激光输出,泵浦非线性晶体PPLT进行频率变换,实现高功率3 m～5 m中红外激光输出。在电源输入电流30 A、调Q驱动频率10 kHz的条件下,获得最高功率10.6 W的3.9 m中红外激光,1.06 m～3.9 m转化效率为9.5%。实验结果表明:通过双声光调Q技术和LD侧面泵浦双棒串接技术,可以实现4束高重复频率窄脉宽1.06 m偏振激光输出,泵浦PPLT可获得高功率3.9 m中红外激光输出。     

高重复频率Nd∶GdVO4/LBO红光激光器

采用侧面泵浦Nd∶GdVO4晶体的方式,利用I类相位匹配LBO（LiB3O5）晶体进行腔内倍频。腔型采用平凹直腔,利用软件模拟优化谐振腔腔镜曲率半径、腔长以及晶体放置位置等参数,在最大注入电功率750 W时获得9.7 W的671 nm光输出,重复频率10 kHz,发散角7.9 mrad,电-光转换效率约为1.3%。